Net62323: Career Spot 77: JumboTests Updates: Updated: Question in GATE 2012 Chemistry Paper with Solution

Saturday, August 4, 2012

Career Spot 77

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Aug 4th 2012, 13:07

JumboTests Updates

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Aug 4th 2012, 12:06

Statement for Linked Answer Questions 54 and 55: Huckel molecular orbital theory can be applied to the allene radical CH_2 = CH - CH_2

The secular determinant (where $\alpha , \beta$ and E have their usual meanings) is given by

$\Bigg|$ $\overset{a-E}{\underset{0}{- \beta}}$ $\overset{- \beta}{\underset{- \beta}{a-E}}$ $\overset{0}{\underset{a-E}{- \beta}}$ $\Bigg|$
$\Bigg|$ $\overset{a-E}{\underset{0}{\beta}}$ $\overset{\beta}{\underset{\beta}{a-E}}$ $\overset{0}{\underset{a-E}{\beta}}$ $\Bigg|$
$\Bigg|$ $\overset{a-E}{\underset{0}{\beta}}$ $\overset{\beta}{\underset{0}{a-E}}$ $\overset{0}{\underset{a-E}{0}}$ $\Bigg|$
$\Bigg|$ $\overset{a-E}{\underset{0}{0}}$ $\overset{0}{\underset{\beta}{a-E}}$ $\overset{0}{\underset{\beta}{a-E}}$ $\Bigg|$

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